Read e-book online A New Unifying Biparametric Nomenclature that Spans all of PDF

By Seymour B. Elk

ISBN-10: 0444516859

ISBN-13: 9780444516855

Content material:
Preface

, Pages v-x
Chapter 1 - Introduction

, Pages 1-48
Chapter 2 - Non-integer bonds

, Pages 49-114
Chapter three - different major transformations from latest systems

, Pages 115-166
Chapter four - Oxidation numbers

, Pages 167-179
Chapter five - The boranes and comparable aluminum compounds

, Pages 180-205
Chapter 6 - Spiro and comparable compounds

, Pages 206-257
Chapter 7 - Topologically constrained compounds

, Pages 258-268
Chapter eight - Polymers

, Pages 269-292
Chapter nine - Molecular Rearrangement

, Pages 293-303
Index

, Pages I1-I7

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Read Online or Download A New Unifying Biparametric Nomenclature that Spans all of Chemistry. The science of incorporating daily over 2,000 new names to a base of over 42 million compounds while still maintaining order PDF

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Extra info for A New Unifying Biparametric Nomenclature that Spans all of Chemistry. The science of incorporating daily over 2,000 new names to a base of over 42 million compounds while still maintaining order

Example text

Three of these play a major role in establishing a unified system of nomenclature: (1) "alpha" (a) bond: a bond intermediate between no bond and a traditional single bond (2) "beta" (P) bond: a bond intermediate between a traditional single and a double bond (3) "aleph" (X) bond: a bond with bond order near to 1, but with certain properties more closely related to a beta bond than to the traditional single bond. Two other standardized bonds, one an intermediate bond characterized by non-integer bond orders higher than 2 and the other with bond order near to 2, but with certain properties distinct from the traditional double bond, are also postulated.

In other words, rather than using "di" when naming two sets of a "simple" group, "bis" for two sets of a "complex" group, and "bi" for two sets of a ring assembly, where the line separating "simple" vs. "complex" is an unstated heuristic that may be interpreted differently by different persons, as well as similar prefixes of "tri" vs. "tris" vs. "ter" for three, "tetra" vs. tetrakis" vs. , ONLY the simple integer set (which carries no additional connotations) is used. (4) All ordering parameters have a chemical basis (usually atomic number).

The elevated importance for selected atoms (designated as "central") in "inorganic chemistry". In other w^ords, the heuristics of relative importance determined the "clarity" of the defmition. Consequently, in order to formulate a unified nomenclature, one must, at the expense of discarding historical precedent, choose the same perspective for both subdomains. The milieu chosen is a graph theory based one. Harary [102] describes the term "bridge" as a single edge of a connected graph whose removal would disconnect that graph.

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A New Unifying Biparametric Nomenclature that Spans all of Chemistry. The science of incorporating daily over 2,000 new names to a base of over 42 million compounds while still maintaining order by Seymour B. Elk


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