Download PDF by D. D. Eley, Herman Pines, Paul B. Weisz: Advances in Catalysis, Vol. 39

By D. D. Eley, Herman Pines, Paul B. Weisz

ISBN-10: 0120078392

ISBN-13: 9780120078394

(from preface)The different efforts of authors and the extensive scope of insurance undertaken in Advances in Catalysis—indeed, the breadth of catalysis itself—are good characterised via the seven chapters of this quantity. those chapters have been written by way of authors from departments of chemistry, chemical engineering, inorganic and analytical chemistry, fabrics technological know-how, and physics; from a number of universities; from significant commercial laboratories; and from a minimum of 3 institutes devoted in particular to catalysis!

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14 V . P . ZHDANOV 2. The mixed bond-site percolation problem yields a more complex way of constructing irregular lattices. In the framework of this problem, q b and q. (fractions of open bonds and sites of the original lattice) can have any values in the range from 0 to 1 simultaneously. If one analyzes, for example, the bond problem on an irregular lattice formed by blocking sites of the original regular lattice, the average coordination number for the irregular lattice is z = qszo, where zo is the coordination number for the original regular lattice.

D. DESCRIPTION OF DESORPTION (APPROACH 1) During desorption, as the relative vapor pressure is reduced, pore solids in which capillary condensation occurs often show a hysteresis loop. The simplest interpretation of this phenomenon is given by the ink-bottle model (6). In the framework of this model (Fig. 12) the adsorption and desorption processes are controlled, respectively, by the void and neck sizes. Thus, desorption from a given pore occurs at a lower pressure than adsorption. FIG. 12. Ink-bottle pores with cylindrical and tapering bodies.

P . ZHDANOV 2. The mixed bond-site percolation problem yields a more complex way of constructing irregular lattices. In the framework of this problem, q b and q. (fractions of open bonds and sites of the original lattice) can have any values in the range from 0 to 1 simultaneously. If one analyzes, for example, the bond problem on an irregular lattice formed by blocking sites of the original regular lattice, the average coordination number for the irregular lattice is z = qszo, where zo is the coordination number for the original regular lattice.

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Advances in Catalysis, Vol. 39 by D. D. Eley, Herman Pines, Paul B. Weisz


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